304 North Cardinal St.
Dorchester Center, MA 02124
304 North Cardinal St.
Dorchester Center, MA 02124
Engineers on the College of California–San Diego have developed lithium-ion batteries that carry out properly at freezing chilly and scorching scorching temperatures, whereas packing quite a lot of vitality. The researchers completed this feat by creating an electrolyte that isn’t solely versatile and strong all through a large temperature vary, but in addition appropriate with a excessive vitality anode and cathode.
The temperature-resilient batteries are described in a paper printed the week of July 4 in Proceedings of the Nationwide Academy of Sciences (PNAS).
Such batteries may enable electrical automobiles in chilly climates to journey farther on a single cost; they might additionally scale back the necessity for cooling methods to maintain the automobiles’ battery packs from overheating in scorching climates, mentioned Zheng Chen, a professor of Nanoengineering on the UC San Diego Jacobs College of Engineering and senior creator of the research.
“You want excessive temperature operation in areas the place the ambient temperature can attain the triple digits and the roads get even hotter. In electrical automobiles, the battery packs are usually beneath the ground, shut to those scorching roads,” defined Chen, who can also be a college member of the UC San Diego Sustainable Energy and Power Heart. “Additionally, batteries heat up simply from having a present run via throughout operation. If the batteries can’t tolerate this warmup at excessive temperature, their efficiency will shortly degrade.”
In assessments, the proof-of-concept batteries retained 87.5% and 115.9% of their vitality capability at -40 and 50°C (-40 and 122°F), respectively. Additionally they had excessive Coulombic efficiencies of 98.2% and 98.7% at these temperatures, respectively, which implies the batteries can endure extra cost and discharge cycles earlier than they cease working.
The batteries that Chen and colleagues developed are each chilly and warmth tolerant due to their electrolyte. It’s fabricated from a liquid answer of dibutyl ether combined with a lithium salt. A particular characteristic about dibutyl ether is that its molecules bind weakly to lithium ions. In different phrases, the electrolyte molecules can simply let go of lithium ions because the battery runs. This weak molecular interplay, the researchers had found in a earlier research, improves battery efficiency at sub-zero temperatures. Plus, dibutyl ether can simply take the warmth as a result of it stays liquid at excessive temperatures (it has a boiling level of 141°C, or 286°F).
What’s additionally particular about this electrolyte is that it’s appropriate with a lithium-sulfur battery, which is a kind of rechargeable battery that has an anode fabricated from lithium metallic and a cathode fabricated from sulfur. Lithium-sulfur batteries are a vital a part of next-generation battery applied sciences as a result of they promise increased vitality densities and decrease prices. They’ll retailer as much as two instances extra vitality per kilogram than right now’s lithium-ion batteries — this might double the vary of electrical automobiles with none enhance within the weight of the battery pack. Additionally, sulfur is extra ample and fewer problematic to supply than the cobalt utilized in conventional lithium-ion battery cathodes.
However there are issues with lithium-sulfur batteries. Each the cathode and anode are tremendous reactive. Sulfur cathodes are so reactive that they dissolve throughout battery operation. This problem will get worse at excessive temperatures. And lithium metallic anodes are susceptible to forming needle-like buildings known as dendrites that may pierce components of the battery, inflicting it to short-circuit. Consequently, lithium-sulfur batteries solely last as long as tens of cycles.
“If you’d like a battery with excessive vitality density, you usually want to make use of very harsh, difficult chemistry,” mentioned Chen. “Excessive vitality means extra reactions are occurring, which implies much less stability, extra degradation. Making a high-energy battery that’s steady is a troublesome process itself — attempting to do that via a large temperature vary is much more difficult.”
The dibutyl ether electrolyte developed by the UC San Diego group prevents these points, even at excessive and low temperatures. The batteries they examined had for much longer biking lives than a typical lithium-sulfur battery. “Our electrolyte helps enhance each the cathode aspect and anode aspect whereas offering excessive conductivity and interfacial stability,” mentioned Chen.
The group additionally engineered the sulfur cathode to be extra steady by grafting it to a polymer. This prevents extra sulfur from dissolving into the electrolyte.
Subsequent steps embody scaling up the battery chemistry, optimizing it to work at even increased temperatures and additional extending cycle life.
Paper: “Solvent choice standards for temperature-resilient lithium-sulfur batteries.” Co-authors embody Guorui Cai, John Holoubek, Mingqian Li, Hongpeng Gao, Yijie Yin, Sicen Yu, Haodong Liu, Tod A. Pascal and Ping Liu, all at UC San Diego.
This work was supported by an Early Profession College grant from NASA’s House Expertise Analysis Grants Program (ECF 80NSSC18K1512), the Nationwide Science Basis via the UC San Diego Supplies Analysis Science and Engineering Heart (MRSEC, grant DMR-2011924), and the Workplace of Car Applied sciences of the U.S. Division of Power via the Superior Battery Supplies Analysis Program (Battery500 Consortium, contract DE-EE0007764). This work was carried out partly on the San Diego Nanotechnology Infrastructure (SDNI) at UC San Diego, a member of the Nationwide Nanotechnology Coordinated Infrastructure, which is supported by the Nationwide Science Basis (grant ECCS-1542148).
Courtesy of UC San Diego.
Recognize CleanTechnica’s originality and cleantech information protection? Think about changing into a CleanTechnica Member, Supporter, Technician, or Ambassador — or a patron on Patreon.